Benzene → HCID 54222234, compound

HRID 2419550Notes

Reaction equation

HRID 2419550 reaction equation
Cl[C:2]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[CH2:11]Cl)=[O:3].[CH:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[FH:19]>>[F:19][C:2]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[CH2:11][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:3]

Participants

4

Reactant 3

HCID 241BenzeneHCID 14917Hydrofluoric AcidHCID 13434000HCID 13434000, compound

Product 1

HCID 54222234HCID 54222234, compoundYield 52%

Procedure

105 g (0.5 mol) of 2-chloromethylphenyl chloroformate are warmed to 40° C with 195 g (2.5 mols) of benzene in 100 ml of hydrogen fluoride for one hour and to 100° C for a further hour. After distillation in vacuo, 60 g (yield: 52%) of 2-benzylphenyl fluoroformate are obtained. 2nd reaction stage

Sources & evidence

ORD record
ord-8e6da21ca1ff4775870ed7d8270f8bb9
Source dataset
uspto-grants-1978_08
Patent number
US04107186

Reaction notes

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