Sodium Iodide → HCID 178504101, compound

HRID 2419956Notes

Reaction equation

HRID 2419956 reaction equation
[CH3:1][S:2][C:3]([P:5](=[O:12])([O:9][CH2:10][CH3:11])[O:6]CC)=[S:4].[I-].[Na+:14]>O1CCCC1>[CH3:1][S:2][C:3]([P:5](=[O:6])([OH:12])[OH:9])=[S:4].[CH2:10]([Na:14])[CH3:11]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 14364274HCID 14364274, compound

Product 1

HCID 178504101HCID 178504101, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a solution of 2.3 parts of diethyl (methylthio)thiocarbonylphosphonate in 50 parts of dry tetrahydrofuran was added 1.5 parts of sodium iodide. The solution was stirred for 18 hours at room temperature, then warmed on a steam bath for one-half hour. The desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered, m.p. 288° d.

Workup

  1. temperaturewarmed on a steam bath for one-half hour
  2. filtrationThe desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered

Sources & evidence

ORD record
ord-9f4bf8d5455a4e6b913b3da3dcd65aa1
Source dataset
uspto-grants-1978_08
Patent number
US04108626

Reaction notes

Loading…