Ethyl p-methylbenzenesulfonate → HCID 20311111, compound

HRID 2420210Notes

Reaction equation

HRID 2420210 reaction equation
[CH3:1][C:2]1[O:3][C:4]2[C:10]([Cl:11])=[C:9]([CH3:12])[C:8]([Cl:13])=[CH:7][C:5]=2[N:6]=1.[CH2:14]([O:16][S:17]([C:20]1[CH:25]=[CH:24][C:23]([CH3:26])=[CH:22][CH:21]=1)(=[O:19])=[O:18])[CH3:15]>>[C:23]1([CH3:26])[CH:22]=[CH:21][C:20]([S:17]([OH:19])(=[O:16])=[O:18])=[CH:25][CH:24]=1.[CH3:1][CH:2]1[N:6]([CH2:14][CH3:15])[C:5]2[CH:7]=[C:8]([Cl:13])[C:9]([CH3:12])=[C:10]([Cl:11])[C:4]=2[O:3]1

Participants

3

Reactant 2

HCID 6638Ethyl p-methylbenzenesulfonateHCID 144190195,7-Dichloro-2,6-dimethylbenzoxazole

Product 1

HCID 20311111HCID 20311111, compound

Procedure

A mixture of 2.1 g. of 2,6-dimethyl-5,7dichloro-benzoxazole and 2 g. of ethyl-p-toluene-sulfonate was heated at 150° C. for 30 minutes. By cooling, a pick cake was obtained. It was ground in a mortar by washing repeatedly with ethyl ether. The product, thus obtained, was dried and used without further purification for the synthesis of dyes.

Workup

  1. additionA mixture of 2.1 g
  2. temperatureBy cooling
  3. customa pick cake was obtained
  4. washby washing repeatedly with ethyl ether
  5. customThe product, thus obtained
  6. customwas dried
  7. customused without further purification for the synthesis of dyes

Sources & evidence

ORD record
ord-9d9400fc9b4b4a259ff7ef6a37afdcf6
Source dataset
uspto-grants-1978_08
Patent number
US04110116

Reaction notes

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