Dimethylformamide → 2-(2,6-Dichloro-4-nitro-phenylsulfanyl)-napthalene

HRID 2427173Notes

Reaction equation

HRID 2427173 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([N+:10]([O-:12])=[O:11])[CH:5]=[C:6]([Cl:9])[C:7]=1Cl.[CH:13]1[C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[CH:16]=[CH:15][C:14]=1[SH:23].CN(C=O)C>CS(C)=O>[Cl:9][C:6]1[CH:5]=[C:4]([N+:10]([O-:12])=[O:11])[CH:3]=[C:2]([Cl:1])[C:7]=1[S:23][C:14]1[CH:15]=[CH:16][C:17]2[C:22](=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH:13]=1

Participants

5

Reactant 3

HCID 6228DimethylformamideHCID 70582-NaphthalenethiolHCID 883653,4,5-Trichloronitrobenzene

Product 1

HCID 221488772-(2,6-Dichloro-4-nitro-phenylsulfanyl)-napthalene

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

2-(2,6-Dichloro-4-nitro-phenylsulfanyl)-napthalene was synthesized (100%) from 3,4,5-trichloronitrobenzene (Acros) and napthalene-2-thiol (Avocado) in a similar manner as described in example 1 using DMSO as solvent instead of DMF.

Sources & evidence

ORD record
ord-b8b69190b50c4633a2db8d8662e5b825
Source dataset
uspto-grants-2011_06
Patent number
US07968567B2

Reaction notes

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