Potassium Carbonate → HCID 86652717, compound

HRID 244292Notes

Reaction equation

HRID 244292 reaction equation
[NH2:1][C:2]1[C:15]2[C:16]3=[C:17]4[C:12](=[CH:13][CH:14]=2)[CH:11]=[CH:10][CH:9]=[C:8]4[CH:7]=[CH:6][C:5]3=[CH:4][CH:3]=1.C(=O)([O-])[O-].[K+].[K+].Br[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][C:30]([O:32][CH2:33][CH3:34])=[O:31]>C(#N)C>[CH2:33]([O:32][C:30]([CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][NH:1][C:2]1[C:15]2[C:16]3=[C:17]4[C:12](=[CH:13][CH:14]=2)[CH:11]=[CH:10][CH:9]=[C:8]4[CH:7]=[CH:6][C:5]3=[CH:4][CH:3]=1)=[O:31])[CH3:34]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 153521-AminopyreneHCID 117544Ethyl 6-bromohexanoate

Product 1

HCID 86652717HCID 86652717, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A mixture of 1-aminopyrene (5 g), potassium carbonate (15 g) and ethyl 6-bromohexanoate (10 g) in 60 mL acetonitrile was refluxed for 24 hours. The solvent was removed and the product was purified by a silica gel column eluting with EtOAc/hexane.

Workup

  1. temperaturewas refluxed for 24 hours
  2. customThe solvent was removed
  3. customthe product was purified by a silica gel column
  4. washeluting with EtOAc/hexane

Sources & evidence

ORD record
ord-f03269c70b7b45c8a06a84ef212488cc
Source dataset
uspto-grants-2014_02
Patent number
US08658434B2

Reaction notes

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