Ammonia → HCID 178510049, compound

HRID 24803Notes

Reaction equation

HRID 24803 reaction equation
C([N:9]1[C:17]2[C:12](=[CH:13][C:14]([N+:18]([O-:20])=[O:19])=[CH:15][CH:16]=2)[C:11](=[C:21](OC)[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:10]1=[O:30])(=O)C1C=CC=CC=1.[NH2:31][C:32]1[CH:39]=[CH:38][C:35]([C:36]#[N:37])=[CH:34][CH:33]=1.N>CN(C=O)C>[C:36]([C:35]1[CH:38]=[CH:39][C:32]([NH:31]/[C:21](=[C:11]2\[C:10](=[O:30])[NH:9][C:17]3[C:12]\2=[CH:13][C:14]([N+:18]([O-:20])=[O:19])=[CH:15][CH:16]=3)/[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)=[CH:33][CH:34]=1)#[N:37]

Participants

5

Reactant 3

HCID 222AmmoniaHCID 133964-AminobenzonitrileHCID 543392991-Benzoyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone

Product 1

HCID 178510049HCID 178510049, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 77 from 1-benzoyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone and 4-aminobenzonitrile in DMF and subsequent treatment with methanolic ammonia.

Sources & evidence

ORD record
ord-45eebfcfaf5042ff9a9bd22062456481
Source dataset
uspto-grants-2005_02
Patent number
US06855710B2

Reaction notes

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