Cyclohexane → HCID 15029369, compound

HRID 249195Notes

Reaction equation

HRID 249195 reaction equation
[C:1]([N:3]1[C:7](=[O:8])[C:6]([CH:10]([CH3:12])[CH3:11])([CH3:9])[N:5]=[C:4]1[C:13]1[N:21]=[CH:20][CH:19]=[CH:18][C:14]=1[C:15]([O-:17])=[O:16])#[N:2].C([N+](CCCC)(CCCC)CCCC)CCC.C1CCCCC1>C(OCC)(=O)C>[C:1]([N:3]1[C:7](=[O:8])[C:6]([CH:10]([CH3:12])[CH3:11])([CH3:9])[N:5]=[C:4]1[C:13]1[N:21]=[CH:20][CH:19]=[CH:18][C:14]=1[C:15]([OH:17])=[O:16])#[N:2]

Participants

4

Reactant 2

HCID 8078CyclohexaneHCID 18961685HCID 18961685, compound

Product 1

HCID 15029369HCID 15029369, compoundYield 46.2%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Tetrabutylammonium 2-(1-cyano-4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinate (0.36 g, 0.00068 mol) is placed into a mixture of cyclohexane and ethyl acetate for 3 months. The mixture is filtered to yield the title compound as a tan solid (0.09 g, 42%), mp 150°-153° C., identified by IR and NMR spectral analyses.

Workup

  1. filtrationThe mixture is filtered

Sources & evidence

ORD record
ord-769c0544ba124029ab8823c01fd5387d
Source dataset
uspto-grants-1993_05
Patent number
US05213607

Reaction notes

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