Hydrochloric Acid → n-Nonadecyl-n-tetradecyl-n-decylmethylchloride

HRID 2591Notes

Reaction equation

HRID 2591 reaction equation
[CH2:1]([C:20]([CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH3:45])([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[Cl-:46].[Ca+2].[Cl-].Cl>C(Cl)Cl>[CH2:1]([C:20]([Cl:46])([CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH3:45])[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 5284359Calcium ChlorideHCID 19690417n-Nonadecyl-n-tetradecyl-n-decylcarbinol

Product 1

HCID 19690413n-Nonadecyl-n-tetradecyl-n-decylmethylchloride

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

One mole of n-nonadecyl-n-tetradecyl-n-decylcarbinol is added to 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas is slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride is evaporated off to give n-nonadecyl-n-tetradecyl-n-decylmethylchloride.

Workup

  1. washThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
  2. dry with materialThe organic layer is dried with magnesium sulfate
  3. customthe methylene chloride is evaporated off

Sources & evidence

ORD record
ord-5357024e5ff4448eabdc6f4dbebdfb2c
Source dataset
uspto-grants-1998_03
Patent number
US05728907

Reaction notes

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