Potassium Carbonate → HCID 54114920, compound

HRID 259280Notes

Reaction equation

HRID 259280 reaction equation
C(O)(=O)C(O)=O.[Cl:7][C:8]1[CH:30]=[CH:29][C:11]([CH2:12][S:13][CH:14]([CH2:21][S:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:15][N:16]2[CH:20]=[CH:19][N:18]=[CH:17]2)=[CH:10][CH:9]=1.C(=O)([O-])[O-].[K+].[K+]>ClCCl>[Cl:7][C:8]1[CH:9]=[CH:10][C:11]([CH2:12][S:13][CH:14]([CH2:21][S:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:15][N:16]2[CH:20]=[CH:19][N:18]=[CH:17]2)=[CH:29][CH:30]=1

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 68120797HCID 68120797, compound

Product 1

HCID 54114920HCID 54114920, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-[2'-(4"-chlorobenzylthio)-3'-(n-hexylthio)propyl]imidazole oxalate (2.3 g.) in 100 ml. of dichloromethane is shaken with excess potassium carbonate solution until the salt is completely dissolved. The organic layer is then separated, washed with water, dried over magnesium sulfate and evaporated to yield 1-[2'-(4"-chlorobenzylthio)-3'-(n-hexylthio)propyl]imidazole.

Workup

  1. dissolutionis completely dissolved
  2. customThe organic layer is then separated
  3. washwashed with water
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-fc3e70c6709641aaa899f2c7629c1573
Source dataset
uspto-grants-1977_07
Patent number
US04036973

Reaction notes

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