N-(Phenylmethylene)-1-dodecanamine → N-Benzyldodecan-1-amine

HRID 262939Notes

Reaction equation

HRID 262939 reaction equation
[H-].[Al+3].[Li+].[H-].[H-].[H-].[CH:7](=[N:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>O1CCCC1>[CH2:7]([NH:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 89283N-(Phenylmethylene)-1-dodecanamineHCID 21226445Aluminium lithium hydride

Product 1

HCID 232909N-Benzyldodecan-1-amine

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1.9 g (0.05 mol.) of lithium aluminum hydride was dissolved in 80 ml of anhydrous tetrahydrofuran. N-benzylidene-n-dodecylamine was gradually added to the mixture at room temperature and heated at 50°~60° C. for an hour to yield N-benzyl-n-dodecylamine (III). The product was purified by distillation. b.p. 150°~157° C./0.6 mmHg.

Workup

  1. temperatureheated at 50°~60° C. for an hour

Sources & evidence

ORD record
ord-5cf654d0bbcf46f681d5ca41f05cd851
Source dataset
uspto-grants-1979_05
Patent number
US04155872

Reaction notes

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