1-Butanol → n-Butylphosphorodichloridate

HRID 263846Notes

Reaction equation

HRID 263846 reaction equation
[P:1]([Cl:5])(Cl)([Cl:3])=[O:2].[CH2:6]([OH:10])[CH2:7][CH2:8][CH3:9]>C(Cl)(Cl)(Cl)Cl>[CH2:6]([O:10][P:1]([Cl:5])([Cl:3])=[O:2])[CH2:7][CH2:8][CH3:9]

Participants

4

Reactant 2

HCID 2631-ButanolHCID 24813Phosphorus oxychloride

Product 1

HCID 137039n-Butylphosphorodichloridate

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

The desired subtitled compound was prepared substantially in accordance with the procedure detailed in Example 8A, using 1.25 ml (13.5 mmol) of phosphorous oxychloride, 1 g (13.5 mmol) of butanol in 5 ml of carbon tetrachloride to provide a colorless oil.

Workup

  1. customto provide a colorless oil

Sources & evidence

ORD record
ord-c23a89090afc49b7acec677166ba8df0
Source dataset
uspto-grants-1997_07
Patent number
US05646111

Reaction notes

Loading…