m-Chloroperbenzoic acid → HCID 21323323, compound

HRID 26515Notes

Reaction equation

HRID 26515 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH2:12][C:11]3=[N:13][N:14]=[C:15]([S:16][CH3:17])[N:10]3[CH:9]=[CH:8][C:7]=2[CH:18]=1.ClC1C=CC=C(C(OO)=[O:27])C=1>>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH2:12][C:11]3=[N:13][N:14]=[C:15]([S:16]([CH3:17])=[O:27])[N:10]3[CH:9]=[CH:8][C:7]=2[CH:18]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 213234258-methoxy-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine

Product 1

HCID 21323323HCID 21323323, compound

Procedure

By a procedure similar to that described in Example 17, 8-methoxy-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine was reacted with m-chloroperbenzoic acid to obtain 8-methoxy-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from chloroform-methanol), m.p. 241°-242° C.

Sources & evidence

ORD record
ord-a1dca2b110d748d1ae9fbffdc3f3bb94
Source dataset
uspto-grants-1979_04
Patent number
US04150139

Reaction notes

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