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HRID266475

反应详情

EQUATION

反应方程式

HRID 266475 的结构方程式

REACTANTS

反应物

3
结构：CI
HCID6328

Methyl iodide

CH3I

结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：C=CCc1cc(OCC)c2c(c1O)S(=O)(=O)N(Cc1ccccc1)C2=O
HCID70053082

未命名化合物

PRODUCTS

生成物

1
结构：C=CCc1cc(OCC)c2c(c1OC)S(=O)(=O)N(Cc1ccccc1)C2=O
HCID70051638

未命名化合物

收率 92%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

CONDITIONS

反应条件

温度
50 °C

PROCEDURE

实验过程

A mixture of 2-benzyl-4-ethoxy-6-allyl-7-hydroxysaccharin (2.45 g), potassium carbonate (2.76 g) and methyl iodide (1.84 g) in acetone was heated at 50° C. with stirring for two hours, then poured with stirring into ice-water (500 mL). The resulting gooey precipitate crystallized overnight affording 2-benzyl-4-ethoxy-6-allyl-7-methoxysaccharin, 2.35 g, 92% yield, mp 92°-94° C.

WORKUP

后处理

  1. additionpoured
  2. customThe resulting gooey precipitate crystallized overnight