Potassium Hydroxide → HCID 54087479, compound

HRID 268084Notes

Reaction equation

HRID 268084 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[O:14][C:13]([C:15]#[N:16])=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].Cl.[NH2:18][OH:19].[OH-].[K+]>C(O)C>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[O:14][C:13]([C:15](=[N:18][OH:19])[NH2:16])=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 14797Potassium HydroxideHCID 443297Hydroxyamine hydrochlorideHCID 4585939HCID 4585939, compound

Product 1

HCID 54087479HCID 54087479, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 97 g (0.45 mole) of 5-(p-nitrophenyl)-2-furonitrile, 34 g (0.49 mole) of hydroxylamine hydrochloride, 27 g (0.49 mole) of KOH and 1450 ml of absolute ethanol was refluxed for one hour, cooled and filtered. The solid was stirred in dilute HCl/H2O, and was filtered and air dried to yield 86 g (67%). An analytical sample was prepared by drying a sample in the vacuum pistol at room temperature, m.p. 230°.

Workup

  1. temperaturewas refluxed for one hour
  2. temperaturecooled
  3. filtrationfiltered
  4. filtrationwas filtered
  5. customair dried
  6. customto yield 86 g (67%)
  7. customAn analytical sample was prepared
  8. customby drying a sample in the vacuum pistol at room temperature

Sources & evidence

ORD record
ord-e0842219b4354f48b2443c3a95ad8e76
Source dataset
uspto-grants-1976_03
Patent number
US03946049

Reaction notes

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