Methanol → HCID 21549795, compound

HRID 268155Notes

Reaction equation

HRID 268155 reaction equation
[N:1]1[C:8](Br)=[N:7][C:5](Br)=[N:4][C:2]=1[Br:3].[C:10](=[O:13])(O)[O-].[Na+].[CH3:15][OH:16]>O>[Br:3][C:2]1[N:4]=[C:5]([O:16][CH3:15])[N:7]=[C:8]([O:13][CH3:10])[N:1]=1

Participants

5

Reactant 3

HCID 887MethanolHCID 269672,4,6-Tribromo-1,3,5-triazineHCID 516892Sodium Bicarbonate

Product 1

HCID 21549795HCID 21549795, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 3.17 g. (0.01 mole) of cyanuric bromide, 1.78 g sodium bicarbonate and 18 ml. methanol was heated under refluxing conditions with stirring for 2 hours. The mixture was cooled and diluted with 50 ml. water. The product was isolated by filtration, washed with water and dried, giving 1.79 g. of white solid, m.p. 118°-120°C.; crystallized from 75 ml. cyclohexane, m.p. 120°-121°C.

Workup

  1. additionA mixture of 3.17 g
  2. temperatureThe mixture was cooled
  3. additiondiluted with 50 ml
  4. customThe product was isolated by filtration
  5. washwashed with water
  6. customdried
  7. customgiving 1.79 g
  8. customcrystallized from 75 ml

Sources & evidence

ORD record
ord-9951c3e4e1f04a319fe7357ce0e3ff53
Source dataset
uspto-grants-1976_03
Patent number
US03947374

Reaction notes

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