Borane → HCID 54510280, compound

HRID 268179Notes

Reaction equation

HRID 268179 reaction equation
[NH:1]1[CH2:8][CH2:7][CH2:6][C@H:2]1[C:3]([OH:5])=O.[N+:9]([C:12]1[CH:24]=[C:16]2[C:17](O[C:20](=O)[N:21](C)[C:15]2=[CH:14][CH:13]=1)=O)([O-:11])=[O:10].B>O1CCCC1>[CH3:20][N:21]1[C:15]2[CH:14]=[CH:13][C:12]([N+:9]([O-:11])=[O:10])=[CH:24][C:16]=2[CH2:17][N:1]2[CH2:8][CH2:7][CH2:6][CH:2]2[C:3]1=[O:5]

Participants

5

Reactant 3

HCID 6331BoraneHCID 784142H-3,1-Benzoxazine-2,4(1H)-dione, 1-methyl-6-nitro-HCID 145742L-Proline

Product 1

HCID 54510280HCID 54510280, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

This compound is obtained when 1,2,3,11a-tetrahydro- 10-methyl-7-nitro-11H-pyrrolo[2,1-c] [1,4]benzodiazepin-5,11- (10H]-dione (prepared from proline and 5-nitro-N-methylisatoic anhydride by the procedure of Example 1) is treated with 1 M borane in tetrahydrofuran by the procedure of Example 1.

Sources & evidence

ORD record
ord-19c4eaa42ae1422a8786f3ca8fca5a37
Source dataset
uspto-grants-1976_03
Patent number
US03947408

Reaction notes

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