Diethylamine → HCID 86736494, compound

HRID 26983Notes

Reaction equation

HRID 26983 reaction equation
[C:1]([O:4][CH2:5]/[C:6](/[CH2:16][CH2:17]/[CH:18]=[C:19](\[CH3:26])/[CH2:20][CH2:21][CH:22]=[C:23]([CH3:25])[CH3:24])=[CH:7]/[CH2:8][CH2:9]/[C:10](/[CH3:15])=[CH:11]/[C:12]([OH:14])=O)(=[O:3])[CH3:2].C(Cl)(=O)C(Cl)=O.[CH2:33]([NH:35][CH2:36][CH3:37])[CH3:34]>>[CH2:33]([N:35]([CH2:36][CH3:37])[C:12](=[O:14])/[CH:11]=[C:10](\[CH3:15])/[CH2:9][CH2:8]/[CH:7]=[C:6](/[CH2:5][O:4][C:1](=[O:3])[CH3:2])\[CH2:16][CH2:17]/[CH:18]=[C:19](\[CH3:26])/[CH2:20][CH2:21][CH:22]=[C:23]([CH3:25])[CH3:24])[CH3:34]

Participants

4

Reactant 3

HCID 8021DiethylamineHCID 65578Oxalyl chlorideHCID 86736495(E,E,E)-7-acetoxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid

Product 1

HCID 86736494HCID 86736494, compound

Procedure

Following the same manner as in Example 12, 1.0 g of (E,Z,E) and (E,E,E)-7-acetoxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid was converted to the corresponding acid chloride with 1.5 ml of oxalyl chloride and the reaction with 1.0 ml of diethylamine afforded 820 mg of the end product.

Sources & evidence

ORD record
ord-5e56612cfaab49fea244a64f77533b5c
Source dataset
uspto-grants-1979_04
Patent number
US04151357

Reaction notes

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