HRID277340

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6331

Borane

H3B

结构：CC(C)CC1C(=O)OC(Cc2ccccc2)C(=O)N(C)C(CC(C)C)C(=O)OC(C)C(=O)N(C)C(CC(C)C)C(=O)OC(Cc2ccccc2)C(=O)N(C)C(CC(C)C)C(=O)OC(C)C(=O)N1C

HCID22628886

未命名化合物

PRODUCTS

生成物

结构：CC(C)CC1C(=O)OC(C)CN(C)C(CC(C)C)C(=O)OC(Cc2ccccc2)CN(C)C(CC(C)C)C(=O)OC(C)CN(C)C(CC(C)C)C(=O)OC(Cc2ccccc2)CN1C

HCID22628911

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

Similar to Example 1, 4.75 g (5 mmol) of PF 1022 in 10 ml of THF were reacted with 100 ml of a 1 M solution of borane and worked-up. Chromatography gave 0.75 g (17% of theory) of tetrareduction product 8,20-dibenzyl-5,11,17,23-tetraisobutyl-2,4,10,14,16,22-hexamethyl-1,7,13,19-tetraoxa-4,10,16,22-tetraazacyclotetracosan-6,12,18,24-tetraone as a light-yellow viscous oil.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7ec0bba78c1148959448e9628caeb4a6
来源数据集: uspto-grants-2002_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06355615B1
来源说明: uspto-grants-2002_03

反应 SMILES

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