Ammonium Hydroxide → Ammonium 3-nitrophthalamidate

HRID 278028Notes

Reaction equation

HRID 278028 reaction equation
[N+:1]([C:4]1[CH:14]=[CH:13][CH:12]=[C:6]2[C:7]([O:9][C:10](=[O:11])[C:5]=12)=[O:8])([O-:3])=[O:2].[OH-].[NH4+:16]>>[N+:1]([C:4]1[CH:14]=[CH:13][CH:12]=[C:6]([C:7]([NH2:16])=[O:8])[C:5]=1[C:10]([O-:9])=[O:11])([O-:3])=[O:2].[NH4+:1]

Participants

3

Reactant 2

HCID 14923Ammonium HydroxideHCID 216313-Nitrophthalic anhydride

Product 1

HCID 70153617Ammonium 3-nitrophthalamidate

Procedure

100 g (518 mmol) of 3-nitrophthalic anhydride were introduced at RT and treated rapidly with 170 ml of concentrated ammonium hydroxide solution with stirring. The mixture was stirred at RT for 1 h. The precipitate was filtered off and dried in a desiccator. Yield: 95.6 g (88%).

Workup

  1. stirringThe mixture was stirred at RT for 1 h
  2. filtrationThe precipitate was filtered off
  3. customdried in a desiccator

Sources & evidence

ORD record
ord-653eec6fc0354b73b7a2603e545106bb
Source dataset
uspto-grants-2002_03
Patent number
US06358978B1

Reaction notes

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