Hydrazine hydrate (1:1) → 2-amino-2-deoxy-D-glucose hydrazone

HRID 279927Notes

Reaction equation

HRID 279927 reaction equation
Cl.O[CH:3]1[O:11][C@H:10]([CH2:12][OH:13])[C@@H:8]([OH:9])[C@H:6]([OH:7])[C@H:4]1[NH2:5].O.[NH2:15][NH2:16]>CO>[NH2:5][C@H:4]([C@H:6]([C@@H:8]([C@@H:10]([CH2:12][OH:13])[OH:11])[OH:9])[OH:7])[CH:3]=[N:15][NH2:16]

Participants

4

Reactant 2

HCID 24654Hydrazine hydrate (1:1)HCID 2723635(3R,4R,5S,6R)-3-amino-6-(hydroxymethyl)oxane-2,4,5-triol hydrochloride

Product 1

HCID 867407802-amino-2-deoxy-D-glucose hydrazone

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A mixture of 2.0 g of glucosamine hydrochloride, 5 ml of methanol and 5 ml of hydrazine hydrate was stirred overnight and then evaporated to dryness giving 2-amino-2-deoxy-D-glucose hydrazone.

Workup

  1. customevaporated to dryness

Sources & evidence

ORD record
ord-8c52c7456b9d40f2bfc4ba02f8453175
Source dataset
uspto-grants-1986_05
Patent number
US04587331

Reaction notes

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