Acetate → 9-Phenylcarbazole

HRID 285637Notes

Reaction equation

HRID 285637 reaction equation
[Br:20][c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1.[C:60]([O-:61])(=[O:62])[CH3:63].[C:65]([O-:66])(=[O:67])[CH3:68].[CH3:14][C:15]([CH3:16])([O-:17])[CH3:18].[Na+:19].[Pd+2:64].[c:27]1([C:28]2([c:29]3[cH:30][cH:31][cH:32][cH:33][cH:34]3)[CH2:35][C:36]2([P:37]([C:38]([CH3:39])([CH3:40])[CH3:41])[C:42]([CH3:43])([CH3:44])[CH3:45])[CH3:46])[cH:47][cH:48][cH:49][cH:50][cH:51]1.[c:52]1([CH3:53])[c:54]([CH3:55])[cH:56][cH:57][cH:58][cH:59]1.[cH:1]1[cH:2][cH:3][cH:4][c:5]2[c:6]3[cH:7][cH:8][cH:9][cH:10][c:11]3[nH:12][c:13]12>>[cH:1]1[cH:2][cH:3][cH:4][c:5]2[c:6]3[cH:7][cH:8][cH:9][cH:10][c:11]3[n:12](-[c:21]3[cH:22][cH:23][cH:24][cH:25][cH:26]3)[c:13]12

Participants

9

Reactant 8

HCID 175Acetate2×HCID 923Sodium ionHCID 6854CarbazoleHCID 7237O-XyleneHCID 7961BromobenzeneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 45749132-Methylpropan-2-olateHCID 21909131Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphane

Product 1

HCID 708519-Phenylcarbazole

Sources & evidence

ORD record
ord-93779eb37b044e1197adc3a785a3dfd6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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