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HRID2979

反应详情

EQUATION

反应方程式

HRID 2979 的结构方程式

REACTANTS

反应物

3
结构：C=C[CH2][Sn]([CH2]CCC)([CH2]CCC)[CH2]CCC
HCID90628

Allyltributylstannane

C15H32Sn

结构：C[Si](C)(C)CCOCCl
HCID2724271

2-Chloromethyl 2-(trimethylsilyl)ethyl ether

C6H15ClOSi

结构：Cc1ccc(-c2nnn[nH]2)cc1Br
HCID178418249

未命名化合物

PRODUCTS

生成物

1
结构：C=CCc1cc(-c2nnnn2COCC[Si](C)(C)C)ccc1C
HCID69840625

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
70 °C

PROCEDURE

实验过程

A solution of 1.0 mmol of this tetrazole, 2.0 mmol of SEMCl in 10 mL DMF was stirred for 1 h. 2.0 mmol of allyltributyltin and 0.1 mmol of Pd(Ph3)4 was added and heated at 70° C. for 14 h. Chromatography provided N-trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole.