Dimethylformamide → HCID 86657875, compound

HRID 299601Notes

Reaction equation

HRID 299601 reaction equation
[Br:1][c:2]1[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:13][O:14][CH2:15][CH2:16][Si:17]([CH3:18])([CH3:19])[CH3:20])[cH:9][c:10]2[CH:11]=[O:12].[Cu:129][I:130].[F:21][c:22]1[c:23](-[n:29]2[cH:30][n:31][c:32]([Sn:34]([CH2:35][CH2:36][CH2:37][CH3:38])([CH2:39][CH2:40][CH2:41][CH3:42])[CH2:43][CH2:44][CH2:45][CH3:46])[cH:33]2)[cH:24][c:25]([F:28])[cH:26][cH:27]1.[O:47]=[CH:48][N:49]([CH3:50])[CH3:51].[cH:52]1[cH:53][cH:54][c:55]([P:56]([Pd:57]([P:58]([c:59]2[cH:60][cH:61][cH:62][cH:63][cH:64]2)([c:65]2[cH:66][cH:67][cH:68][cH:69][cH:70]2)[c:71]2[cH:72][cH:73][cH:74][cH:75][cH:76]2)([P:77]([c:78]2[cH:79][cH:80][cH:81][cH:82][cH:83]2)([c:84]2[cH:85][cH:86][cH:87][cH:88][cH:89]2)[c:90]2[cH:91][cH:92][cH:93][cH:94][cH:95]2)[P:96]([c:97]2[cH:98][cH:99][cH:100][cH:101][cH:102]2)([c:103]2[cH:104][cH:105][cH:106][cH:107][cH:108]2)[c:109]2[cH:110][cH:111][cH:112][cH:113][cH:114]2)([c:115]2[cH:116][cH:117][cH:118][cH:119][cH:120]2)[c:121]2[cH:122][cH:123][cH:124][cH:125][cH:126]2)[cH:127][cH:128]1>>[c:2]1(-[c:32]2[n:31][cH:30][n:29](-[c:23]3[c:22]([F:21])[cH:27][cH:26][c:25]([F:28])[cH:24]3)[cH:33]2)[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:13][O:14][CH2:15][CH2:16][Si:17]([CH3:18])([CH3:19])[CH3:20])[cH:9][c:10]2[CH:11]=[O:12]

Participants

6

Reactant 5

HCID 6228DimethylformamideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 57516653HCID 57516653, compoundHCID 578296122-bromo-5-((2-(trimethylsilyl)ethoxy)methyl)-5H-pyrrolo[2,3-b]pyrazine-7-carbaldehydeHCID 178420554HCID 178420554, compound

Product 1

HCID 86657875HCID 86657875, compound

Sources & evidence

ORD record
ord-763d3df69fb84e60819e3081d908e522
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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