HRID314537

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6344

Dichloromethane

CH2Cl2

HCID8471

Triethylamine

C6H15N

HCID11776

Triphenylphosphine

C18H15P

2 次

HCID24290

未命名化合物

HCID30165

Iodide ion

I-

HCID66111

Trimethylsilylacetylene

C5H10Si

HCID10823932

未命名化合物

PRODUCTS

生成物

HCID15661134

1,2,3,4-Tetrahydro-4,4-dimethyl-6-[2-(trimethylsilyl)ethynyl]quinoline

C16H23NSi

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1e51a22cead9422e8f03d3eafcbb3634
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (8/10)

反应 SMILES

[CH2:21]([Cl:22])[Cl:23].[CH3:15][Si:16]([CH3:17])([CH3:18])[C:19]#[CH:20].[CH3:1][C:2]1([CH3:13])[CH2:3][CH2:4][NH:5][c:6]2[cH:7][cH:8][c:9]([Br:12])[cH:10][c:11]21.[CH3:24][CH2:25][N:26]([CH2:27][CH3:28])[CH2:29][CH3:30].[I-:14].[Pd:31]([Cl:32])[Cl:33].[c:34]1([P:35]([c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[c:42]2[cH:43][cH:44][cH:45][cH:46][cH:47]2)[cH:48][cH:49][cH:50][cH:51][cH:52]1.[c:53]1([P:54]([c:55]2[cH:56][cH:57][cH:58][cH:59][cH:60]2)[c:61]2[cH:62][cH:63][cH:64][cH:65][cH:66]2)[cH:67][cH:68][cH:69][cH:70][cH:71]1>>[CH3:1][C:2]1([CH3:13])[CH2:3][CH2:4][NH:5][c:6]2[cH:7][cH:8][c:9]([C:20]#[C:19][Si:16]([CH3:15])([CH3:17])[CH3:18])[cH:10][c:11]21