1-Dodecanol → HCID 86739351, compound

HRID 325584Notes

Reaction equation

HRID 325584 reaction equation
[O:1]1[CH2:6][CH2:5][O:4][CH2:3][C:2]1=[O:7].[CH3:8][CH:9]1[C:14](=[O:15])[O:13][CH2:12][C:11](=[O:16])[NH:10]1.C(O)CCCCCCCCCCC.CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.[Sn+2]>C1(C)C=CC=CC=1>[O:1]1[CH2:6][CH2:5][O:4][CH2:3][C:2]1=[O:7].[CH3:8][CH:9]1[C:14](=[O:15])[O:13][CH2:12][C:11](=[O:16])[NH:10]1

Participants

6

Reactant 4

HCID 81931-DodecanolHCID 93182-ethylhexanoic acid tin(II) saltHCID 18233DioxanoneHCID 11815872HCID 11815872, compound

Product 1

HCID 86739351HCID 86739351, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

p-Dioxanone (12.8 g, 0.125 moles), 3-methyl-2,5- morpholinedione (0.5 g, 0.00388 moles), 1-dodecanol (0.0369 g, 0.000198 moles), and a catalytic amount of stannous octoate (0.025 ml of a 0.33 M toluene solution, 0.0000083 moles) are heated and magnetically mixed in a flame and vacuum dried, sealed glass ampoule according to the following temperature/time scheme:

Workup

  1. additionmagnetically mixed in
  2. temperaturea flame
  3. customvacuum dried
  4. customsealed glass ampoule

Sources & evidence

ORD record
ord-4c9a86d310894dbca2769c6e71dfebd8
Source dataset
uspto-grants-1984_04
Patent number
US04441496

Reaction notes

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