1-Dodecanol → HCID 86739352, compound

HRID 325585Notes

Reaction equation

HRID 325585 reaction equation
[O:1]1[CH2:6][CH2:5][O:4][CH2:3][C:2]1=[O:7].[CH3:8][N:9]1[C:14](=[O:15])[CH2:13][O:12][C:11](=[O:16])[CH2:10]1.C(O)CCCCCCCCCCC.CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.[Sn+2]>C1(C)C=CC=CC=1>[O:1]1[CH2:6][CH2:5][O:4][CH2:3][C:2]1=[O:7].[CH3:8][N:9]1[C:14](=[O:15])[CH2:13][O:12][C:11](=[O:16])[CH2:10]1

Participants

6

Reactant 4

HCID 81931-DodecanolHCID 93182-ethylhexanoic acid tin(II) saltHCID 18233DioxanoneHCID 20463711HCID 20463711, compound

Product 1

HCID 86739352HCID 86739352, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

p-Dioxanone (28.5 g, 0.279 moles), N-methyl-2,5- morpholinedione (1.5 g, 0.01162 moles), 1-dodecanol (0.082 g, 0.00044 moles), and a catalytic amount of stannous octoate (0.06 ml of a 0.33 M toluene solution, 0.0000198 moles) are heated and magnetically mixed in a flame and vacuum dried, sealed glass ampule according to the following temperature/time scheme:

Workup

  1. additionmagnetically mixed in
  2. temperaturea flame
  3. customvacuum dried
  4. customsealed glass ampule

Sources & evidence

ORD record
ord-6fc0e53c921340e78ed1e0e606cff725
Source dataset
uspto-grants-1984_04
Patent number
US04441496

Reaction notes

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