Benzene → 3,4-dinitrobenzoyl Chloride

HRID 328746Notes

Reaction equation

HRID 328746 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]=1[N+:13]([O-:15])=[O:14])[C:7](O)=[O:8])([O-:3])=[O:2].C1C=CC=CC=1.C(Cl)(=O)C([Cl:25])=O>N1C=CC=CC=1>[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]=1[N+:13]([O-:15])=[O:14])[C:7]([Cl:25])=[O:8])([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 241BenzeneHCID 107093,4-Dinitrobenzoic acidHCID 65578Oxalyl chloride

Product 1

HCID 118064913,4-dinitrobenzoyl Chloride

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Fifty-three grams (0.25 mole) of 3,4-dinitrobenzoic acid, 500 ml. of benzene, 65 g. (0.51 mole) of oxalyl chloride and 1 ml. of pyridine were reacted according to Example 2 (A), first paragraph, to provide 3,4-dinitrobenzoyl chloride as a crude oil.

Sources & evidence

ORD record
ord-839dba5eea18470c8312ecc4e251e62e
Source dataset
uspto-grants-1977_04
Patent number
US04018790

Reaction notes

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