Isopropylamine → HCID 21439156, compound

HRID 329334Notes

Reaction equation

HRID 329334 reaction equation
[O:1]=[C:2]1[C:8]2[CH:9]=[CH:10][C:11]([CH:13]([CH3:17])[C:14]([OH:16])=[O:15])=[CH:12][C:7]=2[CH:6]=[CH:5][C:4]2[CH:18]=[CH:19][CH:20]=[CH:21][C:3]1=2.[CH:22]([NH2:25])([CH3:24])[CH3:23]>C(OCC)(=O)C>[O:1]=[C:2]1[C:8]2[CH:9]=[CH:10][C:11]([CH:13]([CH3:17])[C:14]([O-:16])=[O:15])=[CH:12][C:7]=2[CH:6]=[CH:5][C:4]2[CH:18]=[CH:19][CH:20]=[CH:21][C:3]1=2.[CH:22]([NH3+:25])([CH3:24])[CH3:23]

Participants

4

Reactant 2

HCID 6363IsopropylamineHCID 1739105H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo-

Product 1

HCID 21439156HCID 21439156, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

0.45 G. of 2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionic acid was dissolved in ethyl acetate and isopropylamine is added dropwise until no more precipitate is formed. The precipitate is filtered off and recrystallized from acetone to afford isopropylammonium 2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionate (m.p. 176°-180° C).

Workup

  1. customis formed
  2. filtrationThe precipitate is filtered off
  3. customrecrystallized from acetone

Sources & evidence

ORD record
ord-700b1925030f4f79a7de0179f80e94f3
Source dataset
uspto-grants-1977_04
Patent number
US04020094

Reaction notes

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