huagongshe.com
HRID336521

反应详情

EQUATION

反应方程式

HRID 336521 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：CC(C)(C)OC(=O)N1CCC2(CC1)CC(OS(C)(=O)=O)C2
HCID22248489

1,1-Dimethylethyl 2-[(methylsulfonyl)oxy]-7-azaspiro[3.5]nonane-7-carboxylate

C14H25NO5S

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)N1CCC2(CC1)CC(N=[N+]=[N-])C2
HCID86660638

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

A solution of 5.90 g (18.47 mmol) of tert-butyl 2-methanesulfonyloxy-7-azaspiro[3.5]nonane-7-carboxylate (WO 2003/084 948) and 3.60 g (55.41 mmol) of sodium azide in 27 mL of N,N-dimethylformamide is refluxed for 12 hours under an inert atmosphere.