Methyl p-toluenesulfonate → HCID 86745141, compound

HRID 345197Notes

Reaction equation

HRID 345197 reaction equation
[CH3:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.[CH3:12][O:13][S:14]([C:17]1[CH:22]=[CH:21][C:20]([CH3:23])=[CH:19][CH:18]=1)(=[O:16])=[O:15]>>[CH3:12][N+:3]1[C:4]2[C:9](=[CH:8][CH:7]=[CH:6][CH:5]=2)[CH:10]=[CH:11][C:2]=1[CH3:1].[CH3:23][C:20]1[CH:21]=[CH:22][C:17]([S:14]([OH:16])(=[O:15])=[O:13])=[CH:18][CH:19]=1

Participants

3

Reactant 2

HCID 6645Methyl p-toluenesulfonateHCID 70602-Methylquinoline

Product 1

HCID 86745141HCID 86745141, compound

Procedure

2-Methyl-quinoline (71.5 pbw) and methyl-p-toluenesulfonate (102.3 pbw) are heated for about 10 minutes at 100° C. An exothermic reaction sets in, in which the mixture is heated to 180.C. After another 10 minutes the mixture is poured onto acetone, filtered with suction, washed with acetone and dried.

Workup

  1. customAn exothermic reaction sets in, in which the mixture
  2. additionAfter another 10 minutes the mixture is poured onto acetone
  3. filtrationfiltered with suction
  4. washwashed with acetone
  5. customdried

Sources & evidence

ORD record
ord-d610caabd6674847a09a87c6df6e813e
Source dataset
uspto-grants-1991_10
Patent number
US05055579

Reaction notes

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