Potassium Carbonate → HCID 13104837, compound

HRID 354591Notes

Reaction equation

HRID 354591 reaction equation
[N+]([O-])(O)=O.[Cl:5][C:6]1[CH:11]=[CH:10][C:9]([CH2:12][CH2:13][C:14]2([CH2:28][N:29]3[CH:33]=[CH:32][N:31]=[CH:30]3)[O:18][CH:17]([CH2:19][O:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=3[Cl:27])[CH2:16][O:15]2)=[CH:8][CH:7]=1.C(=O)([O-])[O-].[K+].[K+]>ClCCl>[Cl:5][C:6]1[CH:7]=[CH:8][C:9]([CH2:12][CH2:13][C:14]2([CH2:28][N:29]3[CH:33]=[CH:32][N:31]=[CH:30]3)[O:18][CH:17]([CH2:19][O:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=3[Cl:27])[CH2:16][O:15]2)=[CH:10][CH:11]=1

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 70530242HCID 70530242, compound

Product 1

HCID 13104837HCID 13104837, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-[[2-(2-(4-Chlorophenyl)ethyl)-4-(2-chlorophenoxymethyl)-1,3-dioxolan-2-yl]methyl]imidazole nitrate (2.0 g) in 100 ml of dichloromethane was shaken with excess dilute potassium carbonate solution until the salt was completely dissolved. The organic layer was then separated, washed twice with water, dried over magnesium sulfate and evaporated to yield 1-[[2-(2-(4-chlorophenyl)ethyl)-4-(2-chlorophenoxymethyl)-1,3-dioxolan-2-yl]methyl]imidazole as an oil.

Workup

  1. dissolutionwas completely dissolved
  2. customThe organic layer was then separated
  3. washwashed twice with water
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-cb6db4a871e84a16a563e29ee49c910d
Source dataset
uspto-grants-1983_03
Patent number
US04375474

Reaction notes

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