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HRID356194

反应详情

EQUATION

反应方程式

HRID 356194 的结构方程式

REACTANTS

反应物

2
结构：O=C(Br)CBr
HCID61147

Acetyl bromide, 2-bromo-

C2H2Br2O

结构：O=C1[C@H]2CCC[C@H]2Nc2ccccc2N1Cc1ccc([N+](=O)[O-])cc1
HCID54563031

未命名化合物

PRODUCTS

生成物

1
结构：O=C1[C@H]2CCC[C@H]2N(C(=O)CBr)c2ccccc2N1Cc1ccc([N+](=O)[O-])cc1
HCID70110396

未命名化合物

收率 37%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCCCCC.CCOC(C)=O
溶剂HCID21226206

未命名化合物

PROCEDURE

实验过程

Using (3aR*,10aS*)-9-(4-nitrobenzyl)-2,3,3a,4,9,10a-hexahydrobenzo[b]cyclopenta[e][1,4]-diazepin-10(1H)-one and bromoacetyl bromide, the titled compound was synthesized in substantially the same manner as in Working Example 185 in a yield of 37%, m.p. 160.5°-161.5° C. (ethyl acetate-hexane).