Methyl Acrylate → HCID 13531084, compound

HRID 359734Notes

Reaction equation

HRID 359734 reaction equation
[CH3:1][C:2]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])[CH3:3].C(N(CC)CC)C.[C:24]([O:28][CH3:29])(=[O:27])[CH:25]=[CH2:26]>CO>[CH3:4][C:2]([C:5]1[CH:10]=[C:9]([S:11][CH2:26][CH2:25][C:24]([O:28][CH3:29])=[O:27])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:1])[CH3:3]

Participants

5

Reactant 3

HCID 7294Methyl AcrylateHCID 8471TriethylamineHCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 13531084HCID 13531084, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a solution of 2,6-bis(1,1-dimethylethyl)-4-mercaptophenol (5.00 g, 0.021 mole) and triethylamine (0.5 ml) in methanol (50 ml) was added methyl acrylate (5.40 g, 0.063 mole). The mixture was stirred under argon at room temperature for about 20 hours. Volatiles were removed in vacuo to give an oil. Chromatography on silica gel and recrystallization from hexane gave the title compound, m.p. 63.5°-65.5°.

Workup

  1. customVolatiles were removed in vacuo
  2. customto give an oil
  3. customChromatography on silica gel and recrystallization from hexane

Sources & evidence

ORD record
ord-88b98579fba24e94b30d48a76a499bd5
Source dataset
uspto-grants-1991_03
Patent number
US05002967

Reaction notes

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