Methylamine → HCID 21637049, compound

HRID 362765Notes

Reaction equation

HRID 362765 reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])O.[CH3:13][NH2:14]>>[CH3:13][NH:14][C@@H:11]1[O:12][C@H:3]([CH2:2][OH:1])[C@@H:5]([OH:6])[C@H:7]([OH:8])[C@H:9]1[OH:10]

Participants

3

Reactant 2

HCID 6329MethylamineHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 21637049HCID 21637049, compound

Procedure

A one necked round bottom flask equipped with a stir bar was charged with glucose (40.0 g, 0.22 mole) and 2.0M methylamine (116.5 ml, 0.23 mole). The mixture was stirred overnight at room temperature (20°-21° C.). A sample was taken and analyzed by gas chromatography after acetylation.

Workup

  1. customA one necked round bottom flask equipped with a stir bar

Sources & evidence

ORD record
ord-4e4bca3768774747a40c2f1f2e73b158
Source dataset
uspto-grants-1999_02
Patent number
US05872111

Reaction notes

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