Hydrochloric Acid → HCID 20239949, compound

HRID 363997Notes

Reaction equation

HRID 363997 reaction equation
[C:1](#[N:5])[C:2]([CH3:4])=[CH2:3].N[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.[ClH:13]>C(#N)C>[Cl:13][C:2]([CH3:4])([CH2:3][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[C:1]#[N:5]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 6115AnilineHCID 31368Methacrylonitrile

Product 1

HCID 20239949HCID 20239949, compoundYield 87.9%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Following the general procedure of Example I, 364 mmols of methacrylonitrile were reacted with 25 mmols of distilled aniline in 30 mL of acetonitrile and in the presence of 38 mmols of concentrated HCl and 2.5 mmols of cuprous oxide. The process resulted in an 87.9% yield of 2-chloro-2-methyl-3-phenylpropionitrile.

Sources & evidence

ORD record
ord-56859a13ca184a808ac73b559244948d
Source dataset
uspto-grants-1986_08
Patent number
US04604243

Reaction notes

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