Tetrahydrofuran → HCID 131714804, compound

HRID 364164Notes

Reaction equation

HRID 364164 reaction equation
[Cl:1][C:2]1[C:15]2[C:14](=O)[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[O:7][C:6]=2[C:5]([N+:17]([O-:19])=[O:18])=[CH:4][CH:3]=1.C1COCC1.[NH:25]([CH2:27][CH2:28][NH:29][CH2:30][CH2:31][OH:32])[NH2:26]>CO>[ClH:1].[N+:17]([C:5]1[CH:4]=[CH:3][C:2]2[N:25]([CH2:27][CH2:28][NH:29][CH2:30][CH2:31][OH:32])[N:26]=[C:14]3[C:13]4[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=4[O:7][C:6]=1[C:15]=23)([O-:19])=[O:18]

Participants

5

Reactant 3

HCID 8028TetrahydrofuranHCID 134138082-[(2-Hydrazinylethyl)amino]ethan-1-olHCID 136890061-Chloro-4-nitro-9H-xanthen-9-one

Product 1

HCID 131714804HCID 131714804, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A suspension of 2.76 g of 1-chloro-4-nitro-9H-xanthen-9-one, 30 ml of THF, 15 ml of methanol and 1.40 g of 2-[(hydrazinoethyl)amino]-ethanol was stirred at room temperature for three days. The precipitate was collected, washed with THF and dried, providing the title compound, mp 262°-64° C. (decomp.).

Workup

  1. customThe precipitate was collected
  2. washwashed with THF
  3. customdried

Sources & evidence

ORD record
ord-b2a2e186eea043ae91c9071fab630ca1
Source dataset
uspto-grants-1986_08
Patent number
US04604390

Reaction notes

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