Potassium Carbonate → HCID 20240225, compound

HRID 364196Notes

Reaction equation

HRID 364196 reaction equation
[CH2:1]([N:3]([CH2:6][CH2:7][NH:8][NH2:9])[CH2:4][CH3:5])[CH3:2].Cl[C:11]1[C:24]2[C:23](=O)[C:22]3[C:17](=[CH:18][CH:19]=[C:20]([O:26][CH2:27][C:28]4[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=4)[CH:21]=3)[S:16][C:15]=2[C:14]([N+:34]([O-:36])=[O:35])=[CH:13][CH:12]=1.C([O-])([O-])=O.[K+].[K+]>C1(C)C(C)=CC=CC=1>[CH2:1]([N:3]([CH2:4][CH3:5])[CH2:6][CH2:7][N:8]1[C:11]2[CH:12]=[CH:13][C:14]([N+:34]([O-:36])=[O:35])=[C:15]3[S:16][C:17]4[CH:18]=[CH:19][C:20]([O:26][CH2:27][C:28]5[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=5)=[CH:21][C:22]=4[C:23]([C:24]=23)=[N:9]1)[CH3:2]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 3028735Ethanamine, N,N-diethyl-2-hydrazino-HCID 20240232HCID 20240232, compound

Product 1

HCID 20240225HCID 20240225, compoundYield 61.1%

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

A mixture of 1.2 g (0.0091 mol) of 2-(diethylaminoethyl)hydrazine, 2.7 g (0.0069 mol) of 1-chloro-4-nitro-7-phenylmethoxy-9H-thioxanthen-9-one, and 0.97 g (0.0069 mol) of powdered K2CO3 in 30 ml of xylene was reacted and 2.0 g of the product was isolated as described in Example 58.

Workup

  1. customwas reacted

Sources & evidence

ORD record
ord-ae4e927aff5f4e179c092956aecad107
Source dataset
uspto-grants-1986_08
Patent number
US04604390

Reaction notes

Loading…