Benzoic Acid → HCID 9870448, compound

HRID 366919Notes

Reaction equation

C(O)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10]1(S)[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[CH2:17]([O:21][C:22]1[CH:27]=[CH:26][C:25]([C:28]([C:31]2[CH:36]=[CH:35][C:34]([O:37][CH2:38][CH:39]3[O:41][CH2:40]3)=[CH:33][CH:32]=2)([CH3:30])[CH3:29])=[CH:24][CH:23]=1)[CH:18]1[O:20][CH2:19]1>>[OH:41][CH:39]([CH2:40][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[CH2:38][O:37][C:34]1[CH:35]=[CH:36][C:31]([C:28]([C:25]2[CH:24]=[CH:23][C:22]([O:21][CH2:17][CH:18]([OH:20])[CH2:19][C:10]3[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=3)=[CH:27][CH:26]=2)([CH3:29])[CH3:30])=[CH:32][CH:33]=1

Participants

Reactant 3

HCID 243Benzoic Acid

HCID 2286Bisphenol A diglycidyl ether

HCID 7969Thiophenol

Product 1

HCID 9870448HCID 9870448, compoundYield 94%

Procedure

A reaction was conducted as described in Example 6 except that benzoic acid and PGE were replaced with 210 mmol of thiophenol and 100 mmol of 2,2-bis(4-glycidyloxyphenyl)propane, respectively. Desired 2,2-bis[4-(2-hydroxy-3-phenylpropyloxy)phenyl]propane was formed in an analytical yield of 94% and isolated in a yield of 90%.

Sources & evidence

ORD record: ord-17eb3ca2aee248a1b7d50b28570210d4
Source dataset: uspto-grants-2000_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06130346

Reaction notes

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