Silver → HCID 86740193, compound

HRID 371073Notes

Reaction equation

HRID 371073 reaction equation
[CH2:1]([S:13]([O-:15])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na+].[N+]([O-])([O-])=O.[Ag+:21].[Ag].[Na]>O>[CH2:1]([S:13]([O-:15])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Ag+:21]

Participants

6

Reactant 4

HCID 23954Silver2×HCID 24470Silver NitrateHCID 5360545SodiumHCID 23682396HCID 23682396, compound2×

Product 1

HCID 86740193HCID 86740193, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Using the material from Example 2, 7 g of sodium dodecylsulfinate was dissolved in 300 ml H2O at 32° C. A silver solution was prepared by adding 7 ml of 3N AgNO3 to 200 ml H2O. With stirring between additions, the silver solution was added in four 50 ml portions to allow reaction to convert from the sodium salt to the silver salt. The reaction mixture at 32° C. gave a pH of 3.8 and a pAg of 6.3. The product was filtered, washed with four 100 ml portions of H2O, and dried.

Workup

  1. customreaction
  2. customThe reaction mixture at 32° C. gave a pH of 3.8
  3. filtrationThe product was filtered
  4. washwashed with four 100 ml portions of H2O
  5. customdried

Sources & evidence

ORD record
ord-60dd5a988aaa49c18fc25e09297f348b
Source dataset
uspto-grants-1985_07
Patent number
US04529689

Reaction notes

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