反应详情

A 300 ml autoclave was charged with 5.8g (5 millimoles) of tetrakis (triphenylphosphine) palladium, 1.8g (13.3 millimoles) of triallylamine and 80ml of N-methyl pyrrolidone as a solvent. Oxygen was removed from the autoclave by a nitrogen purge and then ammonia was added with stirring until the internal pressure reached 3.87 Kg/cm. The reactor was then heated with stirring to 100° C (pressure - 10.19 kg/cm) and subsequently to 130° C (pressure - 13.34 kg/cm). At 100° C the reaction was very slow but after 30 minutes at 130° C the triallylamine had reacted to form 5.2 millimoles of monoallylamine and 6.6 millimoles of diallylamine.

1. customOxygen was removed from the autoclave by a nitrogen
2. custompurge
3. additionammonia was added
4. temperatureThe reactor was then heated
5. stirringwith stirring to 100° C (pressure - 10.19 kg/cm)
6. customsubsequently to 130° C
7. customthe triallylamine had reacted