Ammonium Hydroxide → HCID 178475091, compound

HRID 379081Notes

Reaction equation

HRID 379081 reaction equation
C([O:5][C:6](=[O:26])[C@H:7]([CH2:16][CH2:17][CH2:18][CH2:19][NH:20][CH:21]=[N:22][O:23][CH2:24][CH3:25])[NH:8]C(OC(C)(C)C)=O)(C)(C)C.Cl.Cl.N=COCNCCC[C@@H](C(O)=O)N.[OH-].[NH4+]>CO>[CH2:24]([O:23][N:22]=[CH:21][NH:20][CH2:19][CH2:18][CH2:17][CH2:16][C@@H:7]([C:6]([OH:26])=[O:5])[NH2:8])[CH3:25]

Participants

5

Reactant 3

HCID 14923Ammonium HydroxideHCID 86583873N5-(iminomethoxymethyl)-L-ornithine dihydrochlorideHCID 178475093HCID 178475093, compound

Product 1

HCID 178475091HCID 178475091, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

From 1.3 g (3.17 mmol) N2-(tert-butoxycarbonyl)-N6-(ethoxyiminomethyl)-L-lysine tert-butyl ester hydrohloride was prepared 0.82 g (89%) N6-(ethoxyiminomethy)-L-lysine dihydrochloride by the method described above for the preparaton of N5-(iminomethoxymethyl)-L-ornithine dihydrochloride. TLC (4% ammonium hydroxide: methanol) Rf=024. Mass spectrum (CI) 218 (MH+, 92%).

Sources & evidence

ORD record
ord-7fb0e9ea1fb54711a3629686450e0162
Source dataset
uspto-grants-2001_10
Patent number
US06297276B1

Reaction notes

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