2-Ethylhexyl acrylate → HCID 22034350, compound

HRID 394436Notes

Reaction equation

HRID 394436 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([C:8]([OH:10])=[O:9])[CH2:6]C.[C:11](O[CH2:16][CH:17]([CH2:22]C)[CH2:18][CH2:19][CH2:20]C)(=O)C=C.[C:24](=O)([O-])[O-].[Cs+].[Cs+]>C(#N)C>[CH3:11][C:8]([CH3:5])=[O:10].[CH2:18]([C:19]([CH3:20])=[O:9])[CH:17]([CH3:22])[CH3:16].[CH2:5]([C:8]([CH3:24])=[O:10])[CH3:6].[C:8]1(=[O:10])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5]1

Participants

5

Reactant 3

HCID 76362-Ethylhexyl acrylateHCID 86972-Ethylhexanoic AcidHCID 10796Cesium carbonate

Product 1

HCID 22034350HCID 22034350, compoundYield 99%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A procedure similar to that of Example 2 was used for the reaction with 2-EHA. Starting from the TAIT product described in the preceding paragraph (1.0 g, ca. 4.5 mmol), 2-ethylhexyl acrylate (0.82 g, 4.5 mmol) and cesium carbonate (0.75 g, 2.25 mmol) in acetonitrile (20 mL), the product was isolated as a yellow oil and solid mixture (1.8 g, 99 %). IR: 3325, 2933, 2860, 1732, 1480 cm−1.

Sources & evidence

ORD record
ord-86a0ae01e9da48f097884670e8dd499c
Source dataset
uspto-grants-2003_08
Patent number
US06602831B2

Reaction notes

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