Hydrochloric Acid → 1-(4-Bromophenyl)-2,4,4,4-tetrafluoro-1,3-butanedione

HRID 394876Notes

Reaction equation

HRID 394876 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:11])[CH2:9][F:10])=[CH:4][CH:3]=1.O1CCCC1.C[Si](C)(C)[N-][Si](C)(C)C.[Li+].[F:27][C:28]([F:37])([F:36])[C:29](N1C=CN=C1)=[O:30].Cl>O1CCCC1>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([C:8](=[O:11])[CH:9]([F:10])[C:29](=[O:30])[C:28]([F:37])([F:36])[F:27])=[CH:6][CH:7]=1

Participants

6

Procedure

To a solution of 1-(4-bromophenyl)-2-fluoro-1-ethanone (3.54 g, 16.3 mmol) in tetrahydrofuran (50 ml) was added dropwise 1M lithium hexamethyldisilazide tetrahydrofuran solution (19.6 ml, 19.6 mmol) at −78° C. After stirring for 45 min., N-trifluoroacetylimidazole (2.3 ml, 19.6 mmol) was added. The resulting mixture was allowed to warm up to room temperature and stirred for 1.5 hr. The mixture was acidified with 2M hydrochloric acid and extracted with diethyl ether (300 ml). The separated organic layer was washed with water (100 ml×3) and dried over magnesium sulfate. The solution was evaporated to give 5.2 g of 1-(4-bromophenyl)-2,4,4,4-tetrafluoro-1,3-butanedione as a brown oil. This residue was heated with 5-hydrazino-2-pyrisinesulfonamide hydrochloride (1.10 g, 4.89 mmol) at refluxing temperature for 18 hr. After evaporation, the obtained residue was chromatographed on a column of silica gel (500 g) eluting with ethyl acetate/hexane (1:3 to 1:1) to afford 930 mg (12%) of the title compound as a yellow solid.

Workup

  1. stirringstirred for 1.5 hr
  2. extractionextracted with diethyl ether (300 ml)
  3. washThe separated organic layer was washed with water (100 ml×3)
  4. dry with materialdried over magnesium sulfate
  5. customThe solution was evaporated

Sources & evidence

ORD record
ord-1ee69e49fbab41339900c8f71efd0fdc
Source dataset
uspto-grants-2003_08
Patent number
US06603008B1

Reaction notes

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