Ethyl Acetate → 3,5-Dimethoxy-4-methyl-benzoic acid N-(1-tert-butyl-butyl)-N'-(2-ethyl-3-methoxy-benzoyl)-hydrazide

HRID 39653Notes

Reaction equation

HRID 39653 reaction equation
[C:1]([CH:5]([N:10]([C:23](=[O:35])[C:24]1[CH:29]=[C:28]([O:30][CH3:31])[C:27]([CH3:32])=[C:26]([O:33][CH3:34])[CH:25]=1)[NH:11][C:12](=[O:22])[C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([O:19][CH3:20])[C:14]=1[CH3:21])[CH2:6][CH2:7][CH2:8]C)([CH3:4])([CH3:3])[CH3:2].[C:36](OCC)(=O)C>CCCCCC>[C:1]([CH:5]([N:10]([C:23](=[O:35])[C:24]1[CH:25]=[C:26]([O:33][CH3:34])[C:27]([CH3:32])=[C:28]([O:30][CH3:31])[CH:29]=1)[NH:11][C:12](=[O:22])[C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([O:19][CH3:20])[C:14]=1[CH2:21][CH3:36])[CH2:6][CH2:7][CH3:8])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 8857Ethyl AcetateHCID 66764497HCID 66764497, compound

Product 1

HCID 667643843,5-Dimethoxy-4-methyl-benzoic acid N-(1-tert-butyl-butyl)-N'-(2-ethyl-3-methoxy-benzoyl)-hydrazide

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

RG-115852, 3,5-dimethoxy-4-methyl-benzoic acid N-(1-tert-butyl-pentyl)-N′-(3-methoxy-2-methyl-benzoyl)-hydrazide. 1H NMR (CDCl3, 500 MHz), δ (ppm): 7.05 (t, 1H), 7.0 (s, 1H), 6.85 (d, 1H), 6.65 (s, 2H), 6.25 (d, 1H), 4.7 (d, 1H), 3.89 (s, 3H), 3.78 (s, 6H), 2.10 (s, 3H), 1.86 (s, 3H), 1.3-1.6 (br m, 6H), 1.06, 0.99 (2s, 9H), 0.94 (t, 3H); TLC Rf=0.55 (1:1 ethyl acetate:hexane).

Sources & evidence

ORD record
ord-0ac575e2a1c8475b819f398fe580de22
Source dataset
uspto-grants-2013_09
Patent number
US08524948B2

Reaction notes

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