Dichloromethane → HCID 85988586, compound

HRID 412506Notes

Reaction equation

HRID 412506 reaction equation
[Cl-:1].[Cl-].[Cl-].[Cl-].[Zr+4:5].[Cl-].[Cl-].[Cl-].[Al+3:9].C(Cl)[Cl:11]>[N+](C)([O-])=O>[Al+3:9].[Cl-:11].[Cl-:1].[Cl-:11].[Cl-:11].[Cl-:11].[Cl-:11].[Cl-:11].[Zr+4:5]

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 6451240Aluminum(III) ChlorideHCID 9856075Zirconium chloride (ZrCl4), (T-4)-

Product 1

HCID 85988586HCID 85988586, compound

Reagents, catalysts & solvents 1

HCID 6375NitromethaneSolvent

Procedure

1.2 g (5.1 mmol) of zirconium tetrachloride and 6.2 g (46.5 mmol) of aluminum trichloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 410 ml of methylene chloride and 23 ml (25.9 g) of nitromethane were added (ratio Zr/nitro compound 1:82.5).

Sources & evidence

ORD record
ord-8b11187b3ec94ad888c5af91e5d386aa
Source dataset
uspto-grants-2003_05
Patent number
US06562916B2

Reaction notes

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