Dichloromethane → HCID 85988586, compound

HRID 412507Notes

Reaction equation

HRID 412507 reaction equation
[Cl-:1].[Cl-].[Cl-].[Cl-].[Zr+4:5].[Cl-].[Cl-].[Cl-].[Al+3:9].C(Cl)[Cl:11]>[N+](C)([O-])=O>[Al+3:9].[Cl-:11].[Cl-:1].[Cl-:11].[Cl-:11].[Cl-:11].[Cl-:11].[Cl-:11].[Zr+4:5]

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 6451240Aluminum(III) ChlorideHCID 9856075Zirconium chloride (ZrCl4), (T-4)-

Product 1

HCID 85988586HCID 85988586, compound

Reagents, catalysts & solvents 1

HCID 6375NitromethaneSolvent

Procedure

0.7 g (3.0 mmol) of zirconium tetrachloride and 7.6 g (57.0 mmol) of aluminum trichloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 480 ml of methylene chloride and 3 ml (3.38 g) of nitromethane were added (ratio Zr/nitro compound 1:18.4).

Sources & evidence

ORD record
ord-ca34c9294c9d49d8a9d2939565ec2598
Source dataset
uspto-grants-2003_05
Patent number
US06562916B2

Reaction notes

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