Dichloromethane → HCID 86585405, compound

HRID 412508Notes

Reaction equation

HRID 412508 reaction equation
[Cl-:1].[Cl-].[Cl-].[Cl-].[Zr+4:5].[Ti:6]([Cl:10])([Cl:9])([Cl:8])[Cl:7].C(Cl)[Cl:12]>[N+](C)([O-])=O>[Cl:7][Ti:6]([Cl:10])([Cl:9])[Cl:8].[Cl-:12].[Cl-:1].[Cl-:7].[Cl-:7].[Zr+4:5]

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 24193Titanium TetrachlorideHCID 9856075Zirconium chloride (ZrCl4), (T-4)-

Product 1

HCID 86585405HCID 86585405, compound

Reagents, catalysts & solvents 1

HCID 6375NitromethaneSolvent

Procedure

1.4 g (6.0 mmol) of zirconium tetrachloride and 10.207 g (53.8 mmol) of titanium tetrachloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 480 ml of methylene chloride and 7 ml (7.89 g) of nitromethane were added (ratio Zr/nitro compound 1:21.5).

Sources & evidence

ORD record
ord-cb5f92a66fae4325a924ce2b1426830e
Source dataset
uspto-grants-2003_05
Patent number
US06562916B2

Reaction notes

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