Dichloromethane → Hafnium Tetrachloride nitromethane

HRID 412509Notes

Reaction equation

[Cl-:1].[Cl-].[Cl-].[Cl-].[Hf+4:5].C(Cl)[Cl:7].[N+:9]([CH3:12])([O-:11])=[O:10]>>[Cl-:7].[Cl-:1].[Cl-:7].[Cl-:7].[Hf+4:5].[N+:9]([CH3:12])([O-:11])=[O:10]

Participants

Reactant 3

HCID 6344Dichloromethane

HCID 6375Nitromethane

HCID 9927068Hafnium chloride (HfCl4) (6CI,8CI); Hafnium chloride; Hafnium tetrachloride; Hafnium(IV) chloride; Hafnium chloride (HfCl4), (T-4)-

Product 1

HCID 22594783Hafnium Tetrachloride nitromethane

Procedure

17.9 g (55.9 mmol) of hafnium tetrachloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 450 ml of methylene chloride and 32 ml (36.1 g) of nitromethane were added (ratio Hf/nitro compound 1:10.6).

Sources & evidence

ORD record: ord-d61610e868ec42f59c2298060b21dbb0
Source dataset: uspto-grants-2003_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06562916B2

Reaction notes

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