Water → N-[2-(9-anthryloxy)ethyl]phthalimide

HRID 414476Notes

Reaction equation

HRID 414476 reaction equation
[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([C:13]=2[O:15][CH2:16][CH2:17]Cl)=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[C:19]1(=[O:29])[NH:23][C:22](=[O:24])[C:21]2=[CH:25][CH:26]=[CH:27][CH:28]=[C:20]12.[K].O>CN(C)C=O>[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([C:13]=2[O:15][CH2:16][CH2:17][N:23]2[C:22](=[O:24])[C:21]4=[CH:25][CH:26]=[CH:27][CH:28]=[C:20]4[C:19]2=[O:29])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 962WaterHCID 212808202-(9-Anthryloxy)ethyl chlorideHCID 24194345Phthalimide potassium salt

Product 1

HCID 14373233N-[2-(9-anthryloxy)ethyl]phthalimide

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

2-(9-Anthryloxy)ethyl chloride (7.0 g) and potassium phthalimide (2.8 g) were heated to 130° C. in dimethylformamide (70 ml) for 7 hours. The cooled solution was added to water and extracted with ethyl acetate. The extract was dried and evaporated to yield N-[2-(9-anthryloxy)ethyl]phthalimide.

Workup

  1. extractionextracted with ethyl acetate
  2. customThe extract was dried
  3. customevaporated

Sources & evidence

ORD record
ord-99badd7e088745e7b0623acc33b34423
Source dataset
uspto-grants-1988_12
Patent number
US04792551

Reaction notes

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