Allyl glycidyl ether → HCID 131729423, compound

HRID 425135Notes

Reaction equation

HRID 425135 reaction equation
[NH:1]([CH2:6][C:7]([OH:9])=[O:8])[CH2:2][C:3]([OH:5])=[O:4].[OH-].[Na+].[CH2:12]([O:16][CH2:17][CH:18]=[CH2:19])[CH:13]1[O:15][CH2:14]1>O>[CH2:12]([O:16][CH2:17][CH:18]=[CH2:19])[CH:13]1[O:15][CH2:14]1.[NH:1]([CH2:6][C:7]([OH:9])=[O:8])[CH2:2][C:3]([OH:5])=[O:4]

Participants

5

Reactant 3

HCID 7838Allyl glycidyl etherHCID 8897Iminodiacetic acidHCID 14798Sodium Hydroxide2×

Product 1

HCID 131729423HCID 131729423, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
55 °C

Procedure

Into a 2.5 liter SUS separable flask equipped with a reflux condenser and a stirrer, 500.0 g of pure water, 399.3 g of iminodiacetic acid (IDA) and 500.0 g of a 48% aqueous solution of sodium hydroxide (hereinafter, abbreviated as 48% NaOH) were charged, and a temperature of the mixture was adjusted to 55° C. while stirring the mixture. Then, 342.4 g of allyl glycidyl ether (AGE) was slowly added dropwise to a reaction system maintained at 55° C. over two hours while stirring. On completion of adding dropwise, the reaction solution was further aged at 55° C. for 1 hour to produce a 50% aqueous solution of AGE-IDA (hereinafter, abbreviated as 50% AGE-IDA).

Workup

  1. customInto a 2.5 liter SUS separable flask equipped with a reflux condenser and a stirrer
  2. additionwere charged
  3. customwas adjusted to 55° C.
  4. stirringwhile stirring
  5. additionOn completion of adding dropwise

Sources & evidence

ORD record
ord-d8325cadfc4145d18b363241d441a139
Source dataset
uspto-grants-2012_01
Patent number
US08106149B2

Reaction notes

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